| Rank | Rider | Time |
|---|---|---|
| 1 | 05:46:30 | |
| 2 | " | |
| 3 | " | |
| 4 | + 01:55 | |
| 5 | " | |
| 6 | " | |
| 7 | + 02:50 | |
| 8 | " | |
| 9 | + 03:30 | |
| 10 | " | |
| 11 | " | |
| 12 | " | |
| 13 | " | |
| 14 | " | |
| 15 | " | |
| 16 | " | |
| 17 | " | |
| 18 | " | |
| 19 | " | |
| 20 | " | |
| 21 | " | |
| 22 | " | |
| 23 | " | |
| 24 | + 03:55 | |
| 25 | " |
Info
| Date | 29 April 1966 |
| Start |  Liège |
| Finish | Marcinelle |
| Distance | 223.0 km |
| Type | Individual Road Race |
| Average Speed | 38.61 km/h |
Last winners
| 1966 | |
| 1965 | |
| 1964 | |
| 1963 | |
| 1962 |
